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    A study of the formation and application of new chiral water soluble lanthanoid benzoates using real-time infrared spectroscopy

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    Authors
    Andrews, P.
    Fraser, B.
    Gee, W.
    Giera, D.
    Junk, P.
    Massi, Massimiliano
    Tuck, K.
    Date
    2010
    Type
    Journal Article
    
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    Citation
    Andrews, Philip C. and Fraser, Benjamin H. and Gee, William J. and Giera, David and Junk, Peter C. and Massi, Massimiliano and Tuck, Kellie L. 2010. A study of the formation and application of new chiral water soluble lanthanoid benzoates using real-time infrared spectroscopy. Polyhedron. 29 (7): pp. 1764-1770.
    Source Title
    Polyhedron
    DOI
    10.1016/j.poly.2010.02.024
    ISSN
    02775387
    School
    Department of Applied Chemistry
    URI
    http://hdl.handle.net/20.500.11937/15798
    Collection
    • Curtin Research Publications
    Abstract

    A range of water soluble lanthanoid benzoate complexes of composition [Ln(Bz)3(H2O)n] (Ln = La, Gd, Ho and Yb; Bz = 3,5-bis ((R)-2,3-dihydroxypropoxy) benzoate and 3,4,5-tris((R)-2,3-dihydroxypropoxy) benzoate) have been prepared by reaction of lanthanoid bicarbonates with three equivalents of the corresponding optically active benzoic acid in water. Application of [Ln(Bz)3(H2O)n] as asymmetric catalysts for epoxide ring opening reactions has been investigated using styrene oxide, showing complete conversion after 20 h, albeit with no significant enantiomeric excess observed. The formation of the lanthanoid complexes and subsequent catalytic conversion of styrene oxide to phenylethane-1,2-diol were monitored using real-time infrared (RTIR) spectroscopy, yielding information about reaction pathways and intermediates.

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