Hydrogen Desorption from the NaNH2-MgH2 System
| dc.contributor.author | Sheppard, D | |
| dc.contributor.author | Paskevicius, Mark | |
| dc.contributor.author | Buckley, Craig | |
| dc.date.accessioned | 2017-01-30T11:58:47Z | |
| dc.date.available | 2017-01-30T11:58:47Z | |
| dc.date.created | 2012-03-13T20:01:00Z | |
| dc.date.issued | 2011 | |
| dc.identifier.citation | Sheppard, Drew A. and Paskevicius, Mark and Buckley, Craig E. 2011. Hydrogen Desorption from the NaNH2-MgH2 System. The Journal of Physical Chemistry C 115: pp. 8407-8413. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/16951 | |
| dc.identifier.doi | 10.1021/jp200242w | |
| dc.description.abstract |
Ball-milled sodium amide and magnesium hydride (NaNH2:MgH2 = 1:1 molar ratio) desorbs 3.3 wt % of hydrogen between 70 and 335 °C with three desorption events. X-ray diffraction indicates that the hydrogen desorption is associated with two unidentified magnesium-containing phases. Fourier transform infrared spectroscopy indicates that these two phases correspond to an imide and nitride, respectively. Analysis of the desorption products shows a large excess of NaH and MgH2 and that optimizing the starting reagents will increase both the kinetics and the amount of hydrogen desorbed from the system below 165 °C. | |
| dc.publisher | American Chemical Society | |
| dc.title | Hydrogen Desorption from the NaNH2-MgH2 System | |
| dc.type | Journal Article | |
| dcterms.source.volume | 115 | |
| dcterms.source.startPage | 8407 | |
| dcterms.source.endPage | 8413 | |
| dcterms.source.issn | 1932-7447 | |
| dcterms.source.title | The Journal of Physical Chemistry C | |
| curtin.department | Department of Imaging and Applied Physics | |
| curtin.accessStatus | Fulltext not available |