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dc.contributor.authorGreen, K.
dc.contributor.authorSimpson, Peter
dc.contributor.authorCorkery, T.
dc.contributor.authorCifuentes, M.
dc.contributor.authorSamoc, M.
dc.contributor.authorHumphrey, M.
dc.date.accessioned2017-01-30T12:31:36Z
dc.date.available2017-01-30T12:31:36Z
dc.date.created2016-02-01T00:47:11Z
dc.date.issued2012
dc.identifier.citationGreen, K. and Simpson, P. and Corkery, T. and Cifuentes, M. and Samoc, M. and Humphrey, M. 2012. Divergent synthesis of ruthenium alkynyl dendrimers and a two-photon absorption cross-section dendritic effect. Macromolecular Rapid Communications. 33 (6-7): pp. 573-578.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/22475
dc.identifier.doi10.1002/marc.201100770
dc.description.abstract

Ruthenium alkynyl dendrimers up to second generation in size have been prepared by a divergent route and exploiting Sonogashira coupling. The cubic NLO properties have been examined by wide spectral range fs Z-scan studies, revealing an NLO dendritic effect. The significant increase in NLO properties seen on generation increase is maintained when the coefficients are scaled by the number of metal atoms, the dendrimer molecular weights, or the number of "effective" (delocalizable p) electrons in the dendritic structures. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

dc.titleDivergent synthesis of ruthenium alkynyl dendrimers and a two-photon absorption cross-section dendritic effect
dc.typeJournal Article
dcterms.source.volume33
dcterms.source.number6-7
dcterms.source.startPage573
dcterms.source.endPage578
dcterms.source.issn1022-1336
dcterms.source.titleMacromolecular Rapid Communications
curtin.departmentNanochemistry Research Institute
curtin.accessStatusFulltext not available


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