Tuning layer-structured La0.6Sr1.4MnO4+δ into a promising electrode for intermediate-temperature symmetrical solid oxide fuel cells through surface modification
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A K2NiF4-type layer-structured oxide, La0.6Sr1.4MnO4+δ (LSMO4), is tuned into a potential electrode for intermediate-temperature symmetrical solid oxide fuel cells (IT-SSOFCs) through surface modification. Bulk-phase LSMO4 shows high chemical stability under both oxidizing and reducing atmospheres and good thermo-mechanical compatibility with the Sm0.2Ce0.8O1.9 (SDC) electrolyte; however, it exhibits insufficient electro-catalytic activity for both the oxygen reduction reaction (ORR) and oxidation of fuels. Surface modification through infiltration is applied to improve the electro-catalytic activity of the LSMO4-based electrode; both SDC and NiO are explored. The co-modification of the LSMO4 electrode with SDC and NiO is found to provide the best performance. In particular, LSMO4–SDC–NiO shows the highest cathodic performance with an area specific resistance (ASR) of only 0.17 Ω cm2 at 700 °C. Under optimized conditions, a maximum power density of 614 mW cm−2 at 800 °C is achieved for an electrolyte-supported symmetrical SOFC with surface modified LSMO4-based electrodes operating with hydrogen, and a 378 mW cm−2 maximum power output is still achieved at 800 °C when methane is applied as the fuel. The symmetrical cell also shows good operational stability with both hydrogen and methane fuels. Through proper surface modification based on the infiltration method, the results demonstrate that LSMO4 can be developed into favorable electrodes for IT-SSOFCs, which are capable of operating with both hydrogen and hydrocarbon fuels.
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Improved performance of a symmetrical solid oxide fuel cell by swapping the roles of doped ceria and La0.6Sr1.4MnO4+δ in the electrodeShen, J.; Yang, G.; Zhang, Z.; Tadé, M.; Zhou, W.; Shao, Zongping (2017)Symmetrical solid oxide fuel cells (SSOFCs) show many advantageous features as compared with conventional cells with nickel cermet anode and oxide cathode. A K2NiF4-type layer-structured oxide, La0.6Sr1.4MnO4+δ (LSMO4), ...
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