The system of carbon tetrachloride and closed carbon nanotubes analyzed by a combination of molecular simulations, analytical modeling, and adsorption calorimetry
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Authors
Furmaniak, S.
Terzyk, A.
Rychlicki, G.
Wisniewski, M.
Gauden, P.
Kowalczyk, Poitr
Werengowska, K.
Dulska, K.
Date
2010Type
Journal Article
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Furmaniak, S. and Terzyk, A. and Rychlicki, G. and Wisniewski, M. and Gauden, P. and Kowalczyk, P. and Werengowska, K. et al. 2010. The system of carbon tetrachloride and closed carbon nanotubes analyzed by a combination of molecular simulations, analytical modeling, and adsorption calorimetry. Journal of Colloid and Interface Science. 349 (1): pp. 321-330.
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Journal of Colloid and Interface Science
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Collection
Abstract
Using the combined techniques of molecular simulation, simple analytical modeling, and adsorption calorimetry, we propose new models describing adsorption onto closed carbon nanotubes. The models are capable of describing the adsorption isotherms and calorimetric enthalpy of carbon tetrachloride adsorption measured on three different closed carbon nanotubes. It is shown that the assumption of the presence of two types of surface centers (high- and low-energy centers) on external tube surfaces is sufficient to describe experimental adsorption and calorimetric enthalpy data
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