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    A new symmetric solid-oxide fuel cell with La0.8Sr0.2Sc0.2Mn0.8O3-d perovskite oxide as both the anode and cathode

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    Authors
    Zheng, Y.
    Zhang, C.
    Ran, R.
    Cai, R.
    Shao, Zongping
    Farrusseng, D.
    Date
    2009
    Type
    Journal Article
    
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    Citation
    Zheng, Y. and Zhang, C. and Ran, R. and Cai, R. and Shao, Z. and Farrusseng, D. 2009. A new symmetric solid-oxide fuel cell with La0.8Sr0.2Sc0.2Mn0.8O3-d perovskite oxide as both the anode and cathode. Acta Materialia. 57 (4): pp. 1165-1175.
    Source Title
    Acta Materialia
    DOI
    10.1016/j.actamat.2008.10.047
    ISSN
    1359-6454
    School
    Department of Chemical Engineering
    URI
    http://hdl.handle.net/20.500.11937/24907
    Collection
    • Curtin Research Publications
    Abstract

    A novel perovskite-type La0.8Sr0.2Sc0.2Mn0.8O3 (LSSM) oxide was synthesized and evaluated as the electrode material of a symmetric solid-oxide fuel cell. Characterization was done by electrical conductivity, crystal structure stability, redox stability, catalytic activity for methane oxidation and oxygen electro-reduction. LSSM shows greater electrical conductivity than the typical La0.8Sr0.2Cr0.5Mn0.5O3 (LSCM) perovskite oxide under both anode and cathode operating conditions. It also shows excellent chemical and structural stability due to the backbone effect of Sc3+ for the perovskite lattice structure. A symmetric electrolyte-supported cell with 0.3 mm thick scandium-stabilized zirconia electrolyte and LSSM as cathode and anode shows peak power densities of 310 and 130 mW cm2 at 900 °C, respectively, when operating on wet H2 and wet CH4. Stable performance is demonstrated. © 2008 Acta Materialia Inc.

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