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Internally Consistent Ion Volumes and Their Application in Volume-Based Thermodynamics

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Authors
Glasser, Leslie
Jenkins, H.
Date
2008
Type
Journal Article

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Glasser, Leslie and Jenkins, H. Donald Brooke. 2008. Internally Consistent Ion Volumes and Their Application in Volume-Based Thermodynamics. Inorganic Chemistry 47 (14): 6195-6202.
Source Title
Inorganic Chemistry
DOI
Faculty
Department of Applied Chemistry
Division of Engineering, Science and Computing
Faculty of Science
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Abstract

Volume-based thermodynamics? (VBT) relates the thermodynamics of condensed-phase materials to their formula unit (or molecular) volumes, Vm. In order to secure the most accurate representation of these data, the volumes used are to be derived (in order of preference) from crystal structure data or from density or, in the absence of experimental data, estimated by ion-volume summation.