Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes
dc.contributor.author | Andrews, P. | |
dc.contributor.author | Beck, T. | |
dc.contributor.author | Fraser, B. | |
dc.contributor.author | Junk, Peter | |
dc.contributor.author | Massi, Massimiliano | |
dc.date.accessioned | 2017-01-30T13:14:00Z | |
dc.date.available | 2017-01-30T13:14:00Z | |
dc.date.created | 2012-12-03T07:24:54Z | |
dc.date.issued | 2007 | |
dc.identifier.citation | Andrews, Philip C. and Beck, Tobias and Fraser, Benjamin H. and Junk, Peter C. and Massi, Massimiliano. 2007. Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes. Polyhedron 26 (18): pp. 5406-5413. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/29614 | |
dc.identifier.doi | 10.1016/j.poly.2007.08.017 | |
dc.description.abstract |
Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these disubstituted complexes to redistribute forming trisubstituted ones, which is a common behaviour in lanthanoid chemistry. Also, compared to their corresponding lanthanoid carboxylates, all these products are discrete molecular entities forming an extensive hydrogen-bonded and/or pi stacking network rather than hybrid polymeric frameworks. | |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | |
dc.subject | Ions | |
dc.subject | Coordination | |
dc.subject | Chemistry | |
dc.subject | Metal-Organic Frameworks | |
dc.subject | Tetrazolate | |
dc.subject | Analogs | |
dc.subject | Alpha-Amino-Acids | |
dc.subject | Lanthanoid Chemistry | |
dc.subject | Cluster | |
dc.subject | Tetrazolate Complexes | |
dc.subject | Metal Organic Frameworks | |
dc.subject | Hydrogen-Bonded Networks | |
dc.subject | Diagnostic-Tools | |
dc.subject | Ligands | |
dc.title | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes | |
dc.type | Journal Article | |
dcterms.source.volume | 26 | |
dcterms.source.number | 18 | |
dcterms.source.startPage | 5406 | |
dcterms.source.endPage | 5413 | |
dcterms.source.issn | 02775387 | |
dcterms.source.title | Polyhedron | |
curtin.department | ||
curtin.accessStatus | Fulltext not available |