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    TG-FTIR study catalytic effect of inherent metal salt on biomass pyrolysis

    Access Status
    Fulltext not available
    Authors
    He, L.
    Hu, S.
    Sun, L.
    Su, S.
    Jiang, L.
    Song, Yuncai
    Shuai, C.
    Xiang, J.
    Date
    2014
    Type
    Journal Article
    
    Metadata
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    Citation
    He, L. and Hu, S. and Sun, L. and Su, S. and Jiang, L. and Song, Y. and Shuai, C. et al. 2014. TG-FTIR study catalytic effect of inherent metal salt on biomass pyrolysis. Gong cheng re wu li xue bao/Journal of Engineering Thermophysics. 35 (10): pp. 2093-2096.
    Source Title
    Gong cheng re wu li xue bao/Journal of Engineering Thermophysics
    ISSN
    0253-231X
    School
    Fuels and Energy Technology Institute
    URI
    http://hdl.handle.net/20.500.11937/3441
    Collection
    • Curtin Research Publications
    Abstract

    The raw rice straw and leached with deionized water and hydrochloric acid were studied using the method of thermogravimetric(TG) coupled with Fourier transform infrared spectrometry(FTIR) to investigate the catalytic effect of inherent metal salt during biomass pyrolysis. The results indicated alkali metals promoted decomposition reaction comparing to alkaline earth metals especially Ca hindered the reaction. The releasing gas was detected online by FTIR. The main products were CO2, CO, H2O, CH4 and some volatilizable organics contained C=O and C-O-C functional groups. Compared with raw sample, the yield of CO2, CO decreased, CH4 and some volatilizable organics increased after water leaching, all product gas of acid leaching sample were remarkable less than other two samples, which were related with the different catalytic effects of alkali and alkaline earth metals.

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