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    Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials

    Access Status
    Fulltext not available
    Authors
    Chan, J.
    Hoyle, C.
    Lowe, Andrew
    Date
    2009
    Type
    Journal Article
    
    Metadata
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    Citation
    Chan, J. and Hoyle, C. and Lowe, A. 2009. Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials. Journal of the American Chemical Society. 131 (16): pp. 5751-5753.
    Source Title
    Journal of the American Chemical Society
    DOI
    10.1021/ja8099135
    ISSN
    0002-7863
    School
    Nanochemistry Research Institute
    URI
    http://hdl.handle.net/20.500.11937/35667
    Collection
    • Curtin Research Publications
    Abstract

    The first example of highly efficient sequential thiol-ene/thiol-yne reactions conducted in an orthogonal manner is presented and its broad application in the synthesis of polyfunctional materials demonstrated. The anionic chain mechanism of the phosphine-mediated thiol-ene reaction is highlighted, as is the radical-mediated thiol-yne reaction. Kinetic data for a model reaction are presented, followed by a discussion of the synthesis of a range of materials with diverse functionality, including an example of potential biomedical significance. © 2009 American Chemical Society.

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