Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials
| dc.contributor.author | Chan, J. | |
| dc.contributor.author | Hoyle, C. | |
| dc.contributor.author | Lowe, Andrew | |
| dc.date.accessioned | 2017-01-30T13:51:02Z | |
| dc.date.available | 2017-01-30T13:51:02Z | |
| dc.date.created | 2016-09-12T08:36:42Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Chan, J. and Hoyle, C. and Lowe, A. 2009. Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials. Journal of the American Chemical Society. 131 (16): pp. 5751-5753. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/35667 | |
| dc.identifier.doi | 10.1021/ja8099135 | |
| dc.description.abstract |
The first example of highly efficient sequential thiol-ene/thiol-yne reactions conducted in an orthogonal manner is presented and its broad application in the synthesis of polyfunctional materials demonstrated. The anionic chain mechanism of the phosphine-mediated thiol-ene reaction is highlighted, as is the radical-mediated thiol-yne reaction. Kinetic data for a model reaction are presented, followed by a discussion of the synthesis of a range of materials with diverse functionality, including an example of potential biomedical significance. © 2009 American Chemical Society. | |
| dc.publisher | American Chemical Society | |
| dc.title | Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials | |
| dc.type | Journal Article | |
| dcterms.source.volume | 131 | |
| dcterms.source.number | 16 | |
| dcterms.source.startPage | 5751 | |
| dcterms.source.endPage | 5753 | |
| dcterms.source.issn | 0002-7863 | |
| dcterms.source.title | Journal of the American Chemical Society | |
| curtin.department | Nanochemistry Research Institute | |
| curtin.accessStatus | Fulltext not available |
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