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    Determination of trace metals by underpotential deposition–stripping voltammetry at solid electrodes

    Access Status
    Fulltext not available
    Authors
    Herzog, G.
    Arrigan, Damien
    Date
    2005
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Herzog, G. and Arrigan, D. 2005. Determination of trace metals by underpotential deposition–stripping voltammetry at solid electrodes. Trends in Analytical Chemistry. 24 (3): pp. 208-217.
    Source Title
    Trends in Analytical Chemistry
    DOI
    10.1016/j.trac.2004.11.014
    Additional URLs
    http://www.sciencedirect.com/science/article/pii/S0165993605000087
    ISSN
    0165-9936
    URI
    http://hdl.handle.net/20.500.11937/37449
    Collection
    • Curtin Research Publications
    Abstract

    We introduce the behaviour and applications of underpotential deposition (UPD) and its combination with stripping voltammetry (UPD–SV) of metal analytes at solid-electrode surfaces as an important analytical strategy for trace-metal determinations. We review the principles of UPD together with model metal/electrode systems, and discuss analytical utility, including achievement of limits of detection (LODs) and applications to a variety of sample matrices. We present an approach to the alleviation of sample-matrix effects by using surface-protective disorganised monolayer coatings. Finally, we also present the outlook for UPD-SV as an electroanalytical tool.

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