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dc.contributor.authorDe Marco, Roland
dc.contributor.authorJiang, Zhong-Tao
dc.contributor.authorBecker, Thomas
dc.contributor.authorClarke, Graeme
dc.contributor.authorMurgatroyd, G.
dc.contributor.authorPrince, K.
dc.date.accessioned2017-01-30T14:16:17Z
dc.date.available2017-01-30T14:16:17Z
dc.date.created2008-11-12T23:25:07Z
dc.date.issued2006
dc.identifier.citationDe Marco, Roland and Jiang, Zhong-Tao and Becker, Thomas and Clarke, Graeme and Murgatroyd, Gareth and Prince, K. 2006. Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach. Electroanalysis 18 (13-14): 1273-1281.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/38274
dc.identifier.doi10.1002/elan.200503524
dc.description.abstract

In modern materials science, there is a plethora of characterization techniques of materials that can provide valuable insights into the fundamental chemical physics of solid-state devices such as chalcogenide glass ion-selective electrodes (ISEs). In this paper, electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectrometry (XPS) and secondary ion mass spectrometry (SIMS) have been used in the elucidation of the mechanistic chemistry of the cadmium chalcogenide glass ISE. Furthermore, in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD), in situ EIS/SR-GIXRD, along with small angle neutron scattering (SANS), can be used to unravel the complex relationship between the nanostructure, bulk electrical conductivity and concomitant electrochemical reactivity of an iron chalcogenide glass ISE. Significantly, exciting preliminary modified atomic force microscopy (AFM) data utilizing AFM cantilevers with attached microparticles of the copper sensing material jalpaite demonstrate the tremendous potential of selective force ISE-AFM in the imaging of important molecular structures such as the copper ion channels of cell membranes in fish gills and/or phytoplankton

dc.publisherWiley-VCH Verlag GmbH
dc.subjectSurface analysis
dc.subjectIon-selective electrode
dc.subjectMaterials science
dc.subjectChalcogenide glasses
dc.subjectAtomic force microscopy
dc.titleResponse Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
dc.typeJournal Article
dcterms.source.volume18
dcterms.source.number13-14
dcterms.source.startPage1273
dcterms.source.endPage1281
dcterms.source.titleElectroanalysis
curtin.note

Electroanalysis is available online at: Wiley Interscience

curtin.note

http://dx.doi.org/10.1002/elan.200503524

curtin.identifierEPR-897
curtin.accessStatusFulltext not available
curtin.facultyDepartment of Applied Chemistry
curtin.facultyDivision of Engineering, Science and Computing
curtin.facultyFaculty of Science


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