The Electrochemistry of Simple Inorganic Molecules in Room Temperature Ionic Liquids
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This article is published under the Open Access publishing model and distributed under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by-nc/3.0/. Please refer to the licence to obtain terms for any further reuse or distribution of this work. You may not use the material for commercial purposes.
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Abstract
The electrochemistry of simple inorganic compounds in room temperature ionic liquids (RTILs) is reviewed and some new work in this area is presented. This paper focuses on the comparison between electrochemical behaviour in RTILs and in conventional aprotic solvents. Some compounds (iodides, O2, NO2, SO2, NH3) display similar reactions and mechanisms in RTILs as in aprotic solvents (as is observed for organic compounds). However other species (nitrates, PCl3, POCl3) show remarkably different behaviour to traditional solvents. This makes RTILs very promising media for the study of inorganic compounds, and highlights the need for more investigations in this exciting area.
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