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    Study of high-temperature thermal stability of max phases in vacuum

    146112_24573_34th ICACC paper_10-17_Ternary Nitrides.pdf (602.7Kb)
    Access Status
    Open access
    Authors
    Low, It-Meng
    Pang, W.
    Kennedy, S.
    Smith, R.
    Date
    2010
    Type
    Conference Paper
    
    Metadata
    Show full item record
    Citation
    Low, I.M. and Pang, W.K. and Kennedy, S.J. and Smith, R.I. 2010. Study of high-temperature thermal stability of max phases in vacuum, in Sanjay Mathur and Tatsuki Ohji (ed), Proceedings of the 34th International Conference on Advanced Ceramics and Composites, Jan 24 2010, pp. 171-180. Daytona Beach, Florida: American Ceramic Society.
    Source Title
    Proceedings of the 34th International Conference on Advanced Ceramics and Composites
    Source Conference
    Proceedings of the 34th International Conference on Advanced Ceramics and Composites
    School
    Department of Imaging and Applied Physics
    Remarks

    Reprinted with permission of The American Ceramic Society, http://www.ceramics.org/, All rights reserved.

    URI
    http://hdl.handle.net/20.500.11937/3923
    Collection
    • Curtin Research Publications
    Abstract

    The susceptibility of two MAX phases (Ti2AlN and Ti4AlN3) to high-temperature thermal dissociation in a dynamic environment of high-vacuum has been investigated using in-situ neutron diffraction. In high vacuum, these phases decomposed above 1400C through the sublimation of Ti and Al elements, forming a surface coating of TiN. The kinetics of isothermal phase decomposition was modelled using the Avrami equation and the Avrami exponent (n) of isothermal decomposition of Ti2AlN and Ti4AlN3 was determined to be 0.62 and 0.18 respectively. The characteristics of thermal stability and phase transitions in Ti2AlN and Ti4AlN3 are compared and discussed.

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