Catalytic efficiency and stability of cobalt hydroxide for decomposition of ozone and p-chloronitrobenzene in water
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Cobalt hydroxide, a stable and efficient catalyst prepared in the laboratory, has been successfully used in the decomposition of ozone and trace quantities of p-chloronitrobenzene (pCNB) in water. The cobalt hydroxide was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and the Brunauer-Emmet-Teller (BET) method. The decomposition rate of aqueous ozone was increased by 1.527 times in the presence of cobalt hydroxide. Increasing the catalyst loading from 0 to 500 mg/L increased the removal efficiency of pCNB from 59% to 99%. The catalyst morphology and its composition were found to be unaltered after the catalytic reaction. After five successive recycles, the catalyst remained stable in the catalytic ozonation of pCNB.
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