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    The effect of A-site element on CO2 resistance of O2-selective La-based perovskite hollow fibers

    Access Status
    Fulltext not available
    Authors
    Gao, J.
    Lun, Y.
    Hu, Y.
    You, Z.
    Tan, X.
    Wang, S.
    Sunarso, J.
    Liu, Shaomin
    Date
    2017
    Type
    Journal Article
    
    Metadata
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    Citation
    Gao, J. and Lun, Y. and Hu, Y. and You, Z. and Tan, X. and Wang, S. and Sunarso, J. et al. 2017. The effect of A-site element on CO2 resistance of O2-selective La-based perovskite hollow fibers. Journal of Industrial and Engineering Chemistry. 53: pp. 276-284.
    Source Title
    Journal of Industrial and Engineering Chemistry
    DOI
    10.1016/j.jiec.2017.04.036
    ISSN
    1226-086X
    School
    Department of Chemical Engineering
    URI
    http://hdl.handle.net/20.500.11937/53749
    Collection
    • Curtin Research Publications
    Abstract

    Oxygen-selective mixed ionic-electronic conducting (MIEC) ceramic membrane technology enables clean coal combustion and membrane reactor for green chemical synthesis. To be practical in these applications that involve CO2 presence, the membrane materials should have simultaneously high CO2 resistance and oxygen permeation fluxes. This work probed these properties for the perovskite oxide family of La0.6X0.4FeO3-d (X=Mg, Ca, Sr, or Ba), i.e., La0.6Mg0.4FeO3-d (LMF), La0.6Ca0.4FeO3-d (LCF), La0.6Sr0.4FeO3-d (LSF), and La0.6Ba0.4FeO3-d (LBF) in the hollow fiber membrane geometry that is highly suitable for industrial application. LCF hollow fiber displayed the best balance in CO2 resistance and oxygen permeation fluxes.

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