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    Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru

    252683.pdf (11.52Mb)
    Access Status
    Open access
    Authors
    Humphries, Terry
    Sheppard, Drew
    Buckley, Craig
    Date
    2017
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Humphries, T. and Sheppard, D. and Buckley, C. 2017. Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru. Coordination Chemistry Reviews. 342: pp. 19-33.
    Source Title
    Coordination Chemistry Reviews
    DOI
    10.1016/j.ccr.2017.04.001
    ISSN
    0010-8545
    School
    Department of Physics and Astronomy
    Funding and Sponsorship
    http://purl.org/au-research/grants/arc/LP150100730
    URI
    http://hdl.handle.net/20.500.11937/53843
    Collection
    • Curtin Research Publications
    Abstract

    Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional applications; including, smart optical windows, energy storage materials in fuel cells for both stationary and mobile devices, and as thermal energy storage materials for concentrating solar thermal plants. This review concentrates on the molecular structures, thermodynamic properties and other physical properties of the complexes of [NiH4]4-, [FeH6]4-, [CoH5]4- and [RuH6]4-. The synthesized derivatives of these compounds have also been reviewed to give a full overview on the advancement of these systems and will allow for a fresh prospective for future studies to fully understand the physical and chemical nature of these complex transition metal hydrides.

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