Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru
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Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional applications; including, smart optical windows, energy storage materials in fuel cells for both stationary and mobile devices, and as thermal energy storage materials for concentrating solar thermal plants. This review concentrates on the molecular structures, thermodynamic properties and other physical properties of the complexes of [NiH4]4-, [FeH6]4-, [CoH5]4- and [RuH6]4-. The synthesized derivatives of these compounds have also been reviewed to give a full overview on the advancement of these systems and will allow for a fresh prospective for future studies to fully understand the physical and chemical nature of these complex transition metal hydrides.
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Bellosta von Colbe, J.; Ares, J.R.; Barale, J.; Baricco, M.; Buckley, Craig ; Capurso, G.; Gallandat, N.; Grant, D.M.; Guzik, M.N.; Jacob, I.; Jensen, E.H.; Jensen, T.; Jepsen, J.; Klassen, T.; Lototskyy, M.V.; Manickam, K.; Montone, A.; Puszkiel, J.; Sartori, S.; Sheppard, Drew ; Stuart, A.; Walker, G.; Webb, C.J.; Yang, H.; Yartys, V.; Züttel, A.; Dornheim, M. (2019)Metal hydrides are known as a potential efficient, low-risk option for high-density hydrogen storage since the late 1970s. In this paper, the present status and the future perspectives of the use of metal hydrides for ...
Richter, B.; Grinderslev, J.; Moller, Kasper; Paskevicius, Mark; Jensen, T. (2018)© 2018 American Chemical Society. Commencing from metal hydrides, versatile synthesis, purification, and desolvation approaches are presented for a wide range of metal borohydrides and their solvates. An optimized and ...
Complex transition metal hydrides incorporating ionic hydrogen: Synthesis and characterization of Na2Mg2FeH8 and Na2Mg2RuH8Humphries, Terry; Takagi, S.; Li, G.; Matsuo, M.; Sato, T.; Sørby, M.; Deledda, S.; Hauback, B.; Orimo, S. (2015)A new class of quaternary complex transition metal hydrides (Na2Mg2TH8 (T = Fe, Ru)) have been synthesized and their structures determined by combined synchrotron radiation X-ray and powder neutron diffraction. The compounds ...