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    A straightforward treatment of activity in aqueous CaCo3 solutions and the consequences for nucleation theory

    Access Status
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    Authors
    Kellermeier, M.
    Picker, A.
    Kempter, A.
    Cölfen, H.
    Gebauer, Denis
    Date
    2014
    Collection
    • Curtin Research Publications
    Type
    Journal Article
    Metadata
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    Abstract

    The aqueous calcium carbonate system is rigorously investigated with respect to ionic activity. Ideal treatment is found to be a good approximation at relevant concentrations. The data further show that bound CaCO3 species cannot be regarded as «inactive» during nucleation but rather appear to play a key role in the phase-separation process, and that amorphous calcium carbonate (ACC) can be precipitated from much lower levels of supersaturation than previously believed. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    Citation
    Kellermeier, M. and Picker, A. and Kempter, A. and Cölfen, H. and Gebauer, D. 2014. A straightforward treatment of activity in aqueous CaCo3 solutions and the consequences for nucleation theory. Advanced Materials. 26 (5): pp. 752-757.
    Source Title
    Advanced Materials
    URI
    http://hdl.handle.net/20.500.11937/63090
    DOI
    10.1002/adma.201303643
    Department
    Department of Chemistry
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