A straightforward treatment of activity in aqueous CaCo3 solutions and the consequences for nucleation theory
dc.contributor.author | Kellermeier, M. | |
dc.contributor.author | Picker, A. | |
dc.contributor.author | Kempter, A. | |
dc.contributor.author | Cölfen, H. | |
dc.contributor.author | Gebauer, Denis | |
dc.date.accessioned | 2018-02-06T06:15:15Z | |
dc.date.available | 2018-02-06T06:15:15Z | |
dc.date.created | 2018-02-06T05:49:57Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Kellermeier, M. and Picker, A. and Kempter, A. and Cölfen, H. and Gebauer, D. 2014. A straightforward treatment of activity in aqueous CaCo3 solutions and the consequences for nucleation theory. Advanced Materials. 26 (5): pp. 752-757. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/63090 | |
dc.identifier.doi | 10.1002/adma.201303643 | |
dc.description.abstract |
The aqueous calcium carbonate system is rigorously investigated with respect to ionic activity. Ideal treatment is found to be a good approximation at relevant concentrations. The data further show that bound CaCO3 species cannot be regarded as «inactive» during nucleation but rather appear to play a key role in the phase-separation process, and that amorphous calcium carbonate (ACC) can be precipitated from much lower levels of supersaturation than previously believed. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA | |
dc.title | A straightforward treatment of activity in aqueous CaCo3 solutions and the consequences for nucleation theory | |
dc.type | Journal Article | |
dcterms.source.volume | 26 | |
dcterms.source.number | 5 | |
dcterms.source.startPage | 752 | |
dcterms.source.endPage | 757 | |
dcterms.source.issn | 0935-9648 | |
dcterms.source.title | Advanced Materials | |
curtin.department | Department of Chemistry | |
curtin.accessStatus | Fulltext not available |
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