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dc.contributor.authorLiu, B.
dc.contributor.authorSunarso, J.
dc.contributor.authorZhang, Y.
dc.contributor.authorYang, G.
dc.contributor.authorZhou, W.
dc.contributor.authorShao, Zongping
dc.date.accessioned2018-02-19T07:58:34Z
dc.date.available2018-02-19T07:58:34Z
dc.date.created2018-02-19T07:13:37Z
dc.date.issued2018
dc.identifier.citationLiu, B. and Sunarso, J. and Zhang, Y. and Yang, G. and Zhou, W. and Shao, Z. 2018. Highly Oxygen Non-Stoichiometric BaSc0.25Co0.75O3-das a High-Performance Cathode for Intermediate-Temperature Solid Oxide Fuel Cells. ChemElectroChem.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/65523
dc.identifier.doi10.1002/celc.201701309
dc.description.abstract

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Lowering the operating temperature of solid oxide fuel cells (SOFCs) is highly desirable to reduce the cost and increase the lifetime, which relies upon the development of a cathode component with high oxygen reduction reaction (ORR) activity at a lower temperature. Herein, we report the characterization of high-performance BaSc x Co 1-x O 3-d (x=0, 0.125, 0.25, and 0.375) perovskite SOFC cathodes. Unlike BaCoO 3-d , which adopts 2H-hexagonal perovskite structure, the replacement of 25mol% of Co with Sc stabilizes the cubic structure, which also leads to the significant reduction in area specific resistances and their activation energies between 650 and 500°C (for BaSc 0.25 Co 0.75 O 3-d ) relative to the non-doped BaCoO 3-d . In this temperature range, BaSc 0.25 Co 0.75 O 3-d displayed a remarkably high ORR activity compared to Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-d (BSCF), the current cathode benchmark. We attribute such superior ORR performance to the higher oxygen non-stoichiometries of BaSc 0.25 Co 0.75 O 3-d relative to BSCF, which also translates to the higher oxygen bulk diffusion and surface exchange coefficients for the former compared to the latter. As a result, a single fuel cell based on an anode-supported 20µm thick samarium-doped ceria electrolyte and BaSc 0.25 Co 0.75 O 3-d cathode achieved a very high peak power density of 1723mWcm -2 at 650°C. We also demonstrated the possibility to increase the ORR activity of the BaSc 0.25 Co 0.75 O 3-d cathode by impregnation of a low amount of silver.

dc.publisherWiley-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.titleHighly Oxygen Non-Stoichiometric BaSc0.25Co0.75O3-das a High-Performance Cathode for Intermediate-Temperature Solid Oxide Fuel Cells
dc.typeJournal Article
dcterms.source.issn2196-0216
dcterms.source.titleChemElectroChem
curtin.departmentWASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
curtin.accessStatusFulltext not available


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