Rare Earth Borohydrides - Crystal Structures and Thermal Properties
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Rare earth (RE) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high gravimetric hydrogen density. This review illustrates the rich chemistry, structural diversity and thermal properties of borohydrides containing RE elements. In addition, it highlights the decomposition and rehydrogenation properties of composites containing RE-borohydrides, light-weight metal borohydrides such as LiBH4 and additives such as LiH.
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Paskevicius, Mark; Jepsen, L.; Schouwink, P.; Cerný, R.; Ravnsbæk, D.; Filinchuk, Y.; Dornheim, M.; Besenbacher, F.; Jensen, T. (2017)© The Royal Society of Chemistry 2017.A wide variety of metal borohydrides, MBH4, have been discovered and characterized during the past decade, revealing an extremely rich chemistry including fascinating structural ...
Richter, B.; Grinderslev, J.; Moller, Kasper; Paskevicius, Mark; Jensen, T. (2018)© 2018 American Chemical Society. Commencing from metal hydrides, versatile synthesis, purification, and desolvation approaches are presented for a wide range of metal borohydrides and their solvates. An optimized and ...
Hydrogenation properties of lithium and sodium hydride – closo-borate, [B10H10]2− and [B12H12]2−, compositesJensen, S.; Paskevicius, Mark; Hansen, B.; Jakobsen, A.; Møller, K.; White, J.; Allendorf, M.; Stavila, V.; Skibsted, J.; Jensen, T. (2018)© 2018 the Owner Societies. The hydrogen absorption properties of metal closo-borate/metal hydride composites, M2B10H10-8MH and M2B12H12-10MH, M = Li or Na, are studied under high hydrogen pressures to understand the ...