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    Enhancing oxygen reduction reaction activity of perovskite oxides cathode for solid oxide fuel cells using a novel anion doping strategy

    Access Status
    Fulltext not available
    Authors
    Liu, Y.
    Meng, X.
    Yu, F.
    Yin, M.
    Yang, N.
    Meng, B.
    Sofianos, Veronica
    Liu, Shaomin
    Date
    2018
    Type
    Journal Article
    
    Metadata
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    Citation
    Liu, Y. and Meng, X. and Yu, F. and Yin, M. and Yang, N. and Meng, B. and Sofianos, V. et al. 2018. Enhancing oxygen reduction reaction activity of perovskite oxides cathode for solid oxide fuel cells using a novel anion doping strategy. International Journal of Hydrogen Energy. 43 (27): pp. 12328-12336.
    Source Title
    International Journal of Hydrogen Energy
    DOI
    10.1016/j.ijhydene.2018.04.167
    ISSN
    0360-3199
    School
    School of Electrical Engineering, Computing and Mathematical Science (EECMS)
    URI
    http://hdl.handle.net/20.500.11937/68497
    Collection
    • Curtin Research Publications
    Abstract

    Possessing a high oxygen reduction reaction (ORR) activity is one of the most important prerequisites for the cathode to ensure an efficient solid oxide fuel cell. Herein, a highly active cathode is developed by doping the fluorine anion in anion sites of perovskite oxides (ABO3). The electrocatalytic activities of three different cathode samples including the original perovskite La0.6Sr0.4Co0.2Fe0.8O3-d(LSCF), the doped La0.6Sr0.4Co0.2Fe0.8O2.95-dF0.05(LSCFF0.05) and La0.6Sr0.4Co0.2Fe0.8O2.9-dF0.1(LSCFF0.1) are comparatively investigated. The fluorine doped perovskites reveal higher electrochemical performance than the original perovskite. Based on three cathodes of LSCF, LSCFF0.05 and LSCFF0.1 operated at 850 °C, the measured area specific resistance was 0.018, 0.017 and 0.91 O cm2, respectively; and the respective maximum power density of the single fuel cell using the 9-µm-thick YSZ electrolyte was 754, 1005, and 737 mW cm-2. Such performance results vividly indicate that, the obtained perovskite oxyfluoride by doping an optimum amount of F ions can efficiently improve ORR activity and thus is a feasible strategy to develop cathode for high-performance solid oxide fuel cells.

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