Removal of trace organic chemicals in wastewater effluent by UV/H2O2 and UV/PDS
dc.contributor.author | Nihemaiti, M. | |
dc.contributor.author | Miklos, D. | |
dc.contributor.author | Hübner, U. | |
dc.contributor.author | Linden, K. | |
dc.contributor.author | Drewes, J. | |
dc.contributor.author | Croue, Jean-Philippe | |
dc.date.accessioned | 2018-12-13T09:16:00Z | |
dc.date.available | 2018-12-13T09:16:00Z | |
dc.date.created | 2018-12-12T02:47:04Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Nihemaiti, M. and Miklos, D. and H�bner, U. and Linden, K. and Drewes, J. and Croue, J. 2018. Removal of trace organic chemicals in wastewater effluent by UV/H2O2 and UV/PDS. Water Research. 145: pp. 487-497. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/73251 | |
dc.identifier.doi | 10.1016/j.watres.2018.08.052 | |
dc.description.abstract |
© 2018 Elsevier Ltd In this study, we comparatively investigated the degradation of 12 trace organic chemicals (TOrCs) during UV/H2O2 and UV/peroxydisulfate (PDS) processes. Second-order rate constants for the reactions of iopromide, phenytoin, caffeine, benzotriazole, and primidone with sulfate radical (SO4•-) were determined for the first time. Experiments were conducted in buffered pure water and wastewater effluent with spiked TOrCs. UV/PDS degraded all TOrCs more efficiently than UV/H2O2 in buffered pure water due to the higher yield of SO4•- than that of hydroxyl radical (•OH) at the same initial molar dose of PDS and H2O2, respectively. UV/PDS showed higher selectivity toward TOrCs removal than UV/H2O2 in wastewater effluent. Compounds with electron-rich moieties, such as diclofenac, venlafaxine, and metoprolol, were eliminated faster in UV/PDS whereas UV/H2O2 was more efficient in degrading compounds with lower reactivity to SO4•-. The fluence-based rate constants (kobs-UV/H2O2) of TOrCs in wastewater effluent linearly increased as a function of initial H2O2 dose during UV/H2O2, possibly due to the constant scavenging impact of the wastewater matrix on •OH. However, exponential increase of kobs-UV/PDS with increasing PDS dose was observed for most compounds during UV/PDS, suggesting the decreasing scavenging effect of the water matrix (electron-rich site of effluent organic matter (EfOM)) after initial depletion of SO4•- at low PDS dose. Fulvic and humic-like fluorophores appeared to be more persistent during UV/H2O2 compared to aromatic protein and soluble microbial product-like fluorophores. In contrast, UV/PDS efficiently degraded all identified fluorophores and showed less selectivity toward the fluorescent EfOM components. Removal pattern of TOrCs during pilot-scale UV/PDS was consistent with lab-scale experiments, however, overall removal rates were lower due to the presence of higher concentration of EfOM and nitrite. | |
dc.publisher | IWA Publishing | |
dc.title | Removal of trace organic chemicals in wastewater effluent by UV/H2O2 and UV/PDS | |
dc.type | Journal Article | |
dcterms.source.volume | 145 | |
dcterms.source.startPage | 487 | |
dcterms.source.endPage | 497 | |
dcterms.source.issn | 0043-1354 | |
dcterms.source.title | Water Research | |
curtin.department | Curtin Water Quality Research Centre | |
curtin.accessStatus | Fulltext not available |
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