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dc.contributor.authorChester, Ryan
dc.contributor.authorDe Marco, Roland
dc.contributor.authorMocerino, Mauro
dc.contributor.authorOgden, Mark
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.date.accessioned2017-01-30T11:03:15Z
dc.date.available2017-01-30T11:03:15Z
dc.date.created2009-09-13T20:02:00Z
dc.date.issued2009
dc.identifier.citationChester, Ryan and De Marco, Roland and Mocerino, Mauro and Ogden, Mark and Skelton, Brian and White, Allan. 2009. Structures and properties of solvated and unsolvated isopropyl functionalised calix[4]arenes. Supramolecular Chemistry. 21 (6): pp. 479-485.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/7909
dc.identifier.doi10.1080/10610270802308403
dc.description.abstract

The tetra-iso-propyl ethers of calix[4]arene and p-t-butylcalix[4]arene have been isolated in the cone conformation, and structurally characterized as chloroform solvates. Thermogravimetric analysis demonstrated that the parent iso-propylcalix[4]arene solvate is significantly more stable than the p-t-butylcalix[4]arene analogue, retaining the solvent up to a temperature of of 125 °C. It was found that the calix[4]arene ether sublimes at atmospheric pressure, and solvent-free crystals appropriate for structure determination were produced at reduced pressure. The p-t-butylcalix[4]arene ether was also isolated without solvent in the lattice, but in this case the calixarene was crystallized from acetone, as sublimation did not produce crystals of sufficient quality.

dc.publisherTaylor and Francis
dc.subjectThermogravimetric analysis
dc.subjectCalixarene
dc.subjectCrystal structure
dc.titleStructures and properties of solvated and unsolvated isopropyl functionalised calix[4]arenes
dc.typeJournal Article
dcterms.source.volume21
dcterms.source.number6
dcterms.source.startPage479
dcterms.source.endPage485
dcterms.source.issn10610278
dcterms.source.titleSupramolecular Chemistry
curtin.accessStatusOpen access
curtin.facultyDepartment of Applied Chemistry
curtin.facultySchool of Science
curtin.facultyFaculty of Science and Engineering


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