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    Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns.

    Access Status
    Fulltext not available
    Authors
    Mocerino, Mauro
    Tan, Daniel A
    McIldowie, Matthew J
    Massera, Chiara
    Date
    2020
    Type
    Journal Article
    
    Metadata
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    Citation
    Mocerino, M. and Tan, D.A. and McIldowie, M.J. and Massera, C. 2020. Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. European Journal of Organic Chemistry.
    Source Title
    European Journal of Organic Chemistry
    DOI
    10.1002/ejoc.202000874
    ISSN
    1434-193X
    Faculty
    Faculty of Science and Engineering
    School
    School of Molecular and Life Sciences (MLS)
    URI
    http://hdl.handle.net/20.500.11937/80331
    Collection
    • Curtin Research Publications
    Abstract

    Our interest in the potential of chiral tetramethoxy-resorcinarene as agents for chiral recognition has led us to synthesise twelve distally-bridged chiral resorcinarene crowns. The fascinating architecture of these partially-enclosed chiral basket molecules is evident in the solid-state structures which have been determined by single crystal X-ray crystallography. Moreover, the enantiomers of these chiral resorcinarene crowns have been resolved via diastereomeric resolution, with the absolute configuration of the diastereomers being determined by X-ray crystallography. This work enables further exploration of these enantio-pure chiral baskets as possible chiral resolving agents.

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