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    Electrochemistry at the interface between an aqueous droplet and 1,2-dichloroethane

    Access Status
    Fulltext not available
    Authors
    Alam, M.
    Sohail, M.
    De Marco, Roland
    Date
    2012
    Type
    Journal Article
    
    Metadata
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    Citation
    Alam, M. and Sohail, M. and De Marco, R. 2012. Electrochemistry at the interface between an aqueous droplet and 1,2-dichloroethane. Electrochemistry Communications. 19: pp. 142-144.
    Source Title
    Electrochemistry Communications
    DOI
    10.1016/j.elecom.2012.02.044
    ISSN
    1388-2481
    School
    Department of Chemistry
    URI
    http://hdl.handle.net/20.500.11937/9827
    Collection
    • Curtin Research Publications
    Abstract

    Ion transfer in the absence of a dissolved redox couple at the interface between a droplet of water and 1,2-dichloroethane on a Ag/AgCl disc electrode has been studied in this communication. Due to the hemispherical shape of the water droplet, both planar and radial diffusion are contributing to the egress of ions during anodic stripping, while the ingress of ions during cathodic accumulation occurs solely via a planar diffusion mechanism, which was confirmed by changing the scan rates, volume of droplet and electrolyte.

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