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dc.contributor.authorSimpson, Peter
dc.contributor.authorBrown, D.
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.contributor.authorBaker, M.
dc.date.accessioned2017-01-30T11:16:06Z
dc.date.available2017-01-30T11:16:06Z
dc.date.created2015-12-17T20:00:16Z
dc.date.issued2015
dc.identifier.citationSimpson, P. and Brown, D. and Skelton, B. and White, A. and Baker, M. 2015. New Structural Motifs Resulting from Internal Constraints in Chelating Bis(NHC) Ligands: A Dinuclear Ruthenium(II) Complex Featuring an η2-Arene Binding Mode and a Remarkable New Tetrameric Silver(I) Halide Form. Organometallics. 34 (11): pp. 2508-2514.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/9965
dc.identifier.doi10.1021/om5012165
dc.description.abstract

© 2015 American Chemical Society. A novel dinuclear ruthenium(II) complex containing two ortho-xylylene-linked bis(NHC) ligands (NHC = N-heterocyclic carbene) has been synthesized via transmetalation from a silver-NHC complex. Each ruthenium atom in the dinuclear complex is chelated through the two carbene carbon atoms and, unusually, an η2-bound xylylene ring, two separate bis(NHC) units being linked by a Ru(μ-Cl)3Ru core. The same bis(NHC) ligand has yielded a neutral tetranuclear 4:2 AgBr:bis(NHC) complex, where ligand steric constraints seemingly inhibit formation of structures derivative of the more familiar “cubane” or “step” forms, resulting in an interesting new structural type.

dc.publisherAmerican Chemical Society
dc.titleNew Structural Motifs Resulting from Internal Constraints in Chelating Bis(NHC) Ligands: A Dinuclear Ruthenium(II) Complex Featuring an η2-Arene Binding Mode and a Remarkable New Tetrameric Silver(I) Halide Form
dc.typeJournal Article
dcterms.source.volume34
dcterms.source.number11
dcterms.source.startPage2508
dcterms.source.endPage2514
dcterms.source.issn0276-7333
dcterms.source.titleOrganometallics
curtin.departmentNanochemistry Research Institute
curtin.accessStatusFulltext not available


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