A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane
| dc.contributor.author | Veder, J. | |
| dc.contributor.author | Nafady, A. | |
| dc.contributor.author | Clarke, G. | |
| dc.contributor.author | De Marco, Roland | |
| dc.contributor.author | Bond, A. | |
| dc.date.accessioned | 2017-01-30T12:38:28Z | |
| dc.date.available | 2017-01-30T12:38:28Z | |
| dc.date.created | 2016-04-19T19:30:35Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Veder, J. and Nafady, A. and Clarke, G. and De Marco, R. and Bond, A. 2012. A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane. Australian Journal of Chemistry. 65 (3): pp. 236-240. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/23641 | |
| dc.identifier.doi | 10.1071/CH11361 | |
| dc.description.abstract |
The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitrile (0.1 M [NBu4][PF6]) solution containing Zn(NO3)2·6H2O. The in situ SR-GIXRD data along with ex situ IR and Raman spectroscopy results all confirmed the formation of the kinetically favoured phase of Zn[TCNQ]2(H2O)2 as the product. | |
| dc.title | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane | |
| dc.type | Journal Article | |
| dcterms.source.volume | 65 | |
| dcterms.source.startPage | 236 | |
| dcterms.source.endPage | 240 | |
| dcterms.source.issn | 0004-9425 | |
| dcterms.source.title | Australian Journal of Chemistry | |
| dcterms.source.series | Australian Journal of Chemistry | |
| curtin.department | Department of Chemistry | |
| curtin.accessStatus | Fulltext not available |
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