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    A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene

    213124_213124.pdf (725.2Kb)
    Access Status
    Open access
    Authors
    McIldowie, Matthew
    Skelton, B.
    Mocerino, Mauro
    Ogden, Mark
    Date
    2015
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    McIldowie, M. and Skelton, B. and Mocerino, M. and Ogden, M. 2015. A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 82 (1-2): pp. 43-46.
    Source Title
    Journal of Inclusion Phenomena and Macrocyclic Chemistry
    DOI
    10.1007/s10847-015-0475-1
    ISSN
    1388-3127
    School
    Department of Chemistry
    Remarks

    The final publication is available at Springer via http://doi.org/10.1007/s10847-015-0475-1

    URI
    http://hdl.handle.net/20.500.11937/30447
    Collection
    • Curtin Research Publications
    Abstract

    The synthesis and structural characterization of a lanthanum picrate complex of the proximally-substituted calix[4]arene bisamide, 5,11,17,23-tetra-tert-butyl-25,26- bis(diethylcarbamoylmethoxy)-27,28-dihydroxycalix[4] arene (L), is reported. The complex is formulated as [La(L-H)(picrate)2]2.75CH2Cl2 and crystallises with two inequivalent metal complexes in the unit cell. The differing dispositions of the picrate anions in the two complexes suggest that intramolecular interactions between the aromatic rings of the picrate and calixarene are less significant than the forces involved in the crystal packing of the complexes.

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    • Structural Variations in the Complete Series of Lanthanoid Complexes of a Calix[4]arene Trisamide
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      Lanthanoid picrate (pic) complexes of 5,11,17,23-tetra-tert-butyl-25-hydroxy-26,27,28-tris(diethylcarbamoylmethoxy)calix[4]arene (LH) have been synthesised and structurally characterised, to complete this series for all ...
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