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dc.contributor.authorMcIldowie, Matthew
dc.contributor.authorSkelton, B.
dc.contributor.authorMocerino, Mauro
dc.contributor.authorOgden, Mark
dc.date.accessioned2017-01-30T13:19:45Z
dc.date.available2017-01-30T13:19:45Z
dc.date.created2015-01-27T20:00:43Z
dc.date.issued2015
dc.date.submitted2015-02-03
dc.identifier.citationMcIldowie, M. and Skelton, B. and Mocerino, M. and Ogden, M. 2015. A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 82 (1-2): pp. 43-46.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/30447
dc.identifier.doi10.1007/s10847-015-0475-1
dc.description.abstract

The synthesis and structural characterization of a lanthanum picrate complex of the proximally-substituted calix[4]arene bisamide, 5,11,17,23-tetra-tert-butyl-25,26- bis(diethylcarbamoylmethoxy)-27,28-dihydroxycalix[4] arene (L), is reported. The complex is formulated as [La(L-H)(picrate)2]2.75CH2Cl2 and crystallises with two inequivalent metal complexes in the unit cell. The differing dispositions of the picrate anions in the two complexes suggest that intramolecular interactions between the aromatic rings of the picrate and calixarene are less significant than the forces involved in the crystal packing of the complexes.

dc.publisherSpringer Netherlands
dc.subjectLanthanide
dc.subjectCalixarene
dc.subjectCrystal structure
dc.subjectPicrate
dc.titleA lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene
dc.typeJournal Article
dcterms.dateSubmitted2015-01-28
dcterms.source.volume81
dcterms.source.number1-2
dcterms.source.issn1388-3127
dcterms.source.titleJournal of Inclusion Phenomena and Macrocyclic Chemistry
curtin.digitool.pid213124
curtin.note

The final publication is available at Springer via http://doi.org/10.1007/s10847-015-0475-1

curtin.pubStatusPublished
curtin.departmentDepartment of Chemistry
curtin.identifier.scriptidPUB-SE-DAC-JR-86772
curtin.accessStatusOpen access


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