Cellobiose Decomposition in Hot-Compressed Water: Importance of Isomerization Reactions
|dc.identifier.citation||Yu, Yun and Shafie, Zainun Mohd and Wu, Hongwei. 2013. Cellobiose Decomposition in Hot-Compressed Water: Importance of Isomerization Reactions. Industrial & Engineering Chemistry Research. 52 (47): pp. 17006-17014.|
This paper reports an investigation on the fundamental reaction mechanism of cellobiose decomposition in hotcompressed water (HCW) using a continuous reactor system at 225-275 °C. The importance of isomerization reactions to form two cellobiose isomers (i.e., cellobiulose and glucosyl-mannose) as the primary reaction products is clearly demonstrated under the reaction conditions, using a high-performance anion exchange chromatography with pulsed amperometric detection and mass spectrometry (HPAEC-PAD-MS). The results also confirm another two primary reactions take place during cellobiose decomposition in HCW: retro-aldol condensation reaction to produce glucosyl-erythrose (GE) and glycolaldehyde, and hydrolysis reaction to produce glucose. The data show that isomerization and retro-aldol condensation are the dominant primary reactions while hydrolysis of cellobiose is only a minor primary reaction (accounting for ~10-20% of cellobiose decomposition depending on reaction temperature). The results indicate that the reaction solution becomes acidic at the early stage of cellobiose decomposition, most likely due to the formation of organic acids, resulting in the subsequent reactions exhibiting more characteristics of acid-catalyzed reactions. The results further suggest that the formed acidic condition has little catalytic effects onthe primary reactions of cellobiose decomposition, but is effective in catalyzing secondary reactions of various reaction intermediates such as hydrolysis and dehydration reactions to form glucose and 5-HMF, respectively.
|dc.publisher||American Chemical Society|
|dc.title||Cellobiose Decomposition in Hot-Compressed Water: Importance of Isomerization Reactions|
|dcterms.source.title||Industrial & Engineering Chemistry Research|
|curtin.accessStatus||Fulltext not available|